-------------------------------------------------------------
Sorting into ascending alphabetical order by film name.
-------------------------------------------------------------
SELECT film FROM Stars ORDER BY film

   or

SELECT Stars.film FROM Stars ORDER BY Stars.film
-------------------------------------------------------------

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Using the Len() function to find Length of the film name.
-------------------------------------------------------------
SELECT film FROM Stars ORDER BY Len(film)

   or

SELECT Stars.film FROM Stars ORDER BY Len(Stars.film)

   or 

SELECT Stars.film FROM Stars ORDER BY Len([Stars]![film])

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To sort into DESCending order, i.e. reverse order, use DESC
---------------------------------------------------------------
SELECT film FROM Stars ORDER BY film DESC

SELECT Stars.film FROM Stars ORDER BY Stars.film DESC
---------------------------------------------------------------

Note that ascending order is the default order for sorting,
  so if the ORDER BY somefieldName does not specify DESC, then
  the order will be ASCending alphabetical or numerical order.